The Electronic and Adsorption Structures of 2-Mercaptoethanol and Thioglycolic Acid on the Ge(100) Surface
- Authors
- Lee, Hangil
- Issue Date
- Oct-2015
- Publisher
- WILEY-V C H VERLAG GMBH
- Keywords
- Molecular adsorption; High-resolution photoemission spectroscopy; Density functional calculations; Functional group selectivity
- Citation
- BULLETIN OF THE KOREAN CHEMICAL SOCIETY, v.36, no.10, pp 2440 - 2445
- Pages
- 6
- Journal Title
- BULLETIN OF THE KOREAN CHEMICAL SOCIETY
- Volume
- 36
- Number
- 10
- Start Page
- 2440
- End Page
- 2445
- URI
- https://scholarworks.sookmyung.ac.kr/handle/2020.sw.sookmyung/10198
- DOI
- 10.1002/bkcs.10468
- ISSN
- 0253-2964
1229-5949
- Abstract
- The adsorption selectivity of 2-mercaptoethanol (2-ME) and thioglycolic acid (TGA) was studied on the Ge(100)-2x1 surface using high-resolution photoemission spectroscopy (HRPES) and the corresponding density functional theory (DFT) calculations. HRPES analysis results indicated that an OH dissociated SH dissociation bonded structure at low coverage and an O-dative bonded structure at high coverage are the stable adsorption structures of 2-ME on the Ge(100) surface. In addition, a SH dissociated O-B -dative bonded structure at low coverage and a S-dative bonded structure at high coverage are reasonable adsorption structures of TGA on the Ge(100) surface. Through work function measurements, we also confirmed that the forms of the adsorption structures of 2-ME and TGA can be determined by n-type (dissociation-bonded structure) and p-type (dative-bonded structure) properties. Moreover, the adsorption structures of 2-ME and TGA on the Ge(100)-2x1 surface were determined through DFT calculations, and the respective stable adsorption structures, transition-state energy, and reaction pathways were obtained.
- Files in This Item
-
Go to Link
- Appears in
Collections - 이과대학 > 화학과 > 1. Journal Articles
Items in ScholarWorks are protected by copyright, with all rights reserved, unless otherwise indicated.