Ba9Ge3N10: A New Ternary Nitride Containing Isolated Planar Triangular Anions of [GeN3](5-)
DC Field | Value | Language |
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dc.contributor.author | Park, Dong Gon | - |
dc.contributor.author | DiSalvo, Francis J. | - |
dc.date.available | 2021-02-22T14:32:17Z | - |
dc.date.issued | 2008-12 | - |
dc.identifier.issn | 0253-2964 | - |
dc.identifier.issn | 1229-5949 | - |
dc.identifier.uri | https://scholarworks.sookmyung.ac.kr/handle/2020.sw.sookmyung/14113 | - |
dc.description.abstract | A new nitride, Ba9Ge3N10, was obtained as single crystals from constituent elements in molten Na. It crystallizes in space group R-3c (No. 167) with a = 7.9399(2) angstrom, c = 17.282(1) angstrom, and Z = 2. It contains the first example of isolated nitridometallate anions of GeN35- in perfect planar triangular shape. Ge-N bond length is 1.786(8) angstrom, which is significantly shorter than any known Ge-N bonds, ranging from 1.84 angstrom to 1.95 angstrom. Valence bond model suggests partial multiple bonding character of the Ge-N bond, which is the first example of such bonding configuration for Ge-N bond. N-centered polyhedral perspective suggests the structure of Ba9Ge3N10 can be conceived as the cationic framework of [Ba9Ge3N9](3+), whose 1/3 of the octahedral interstitial sites are occupied by N3- anions. | - |
dc.format.extent | 6 | - |
dc.language | 영어 | - |
dc.language.iso | ENG | - |
dc.publisher | KOREAN CHEMICAL SOC | - |
dc.title | Ba9Ge3N10: A New Ternary Nitride Containing Isolated Planar Triangular Anions of [GeN3](5-) | - |
dc.type | Article | - |
dc.publisher.location | 대한민국 | - |
dc.identifier.doi | 10.5012/bkcs.2008.29.12.2413 | - |
dc.identifier.scopusid | 2-s2.0-60149104240 | - |
dc.identifier.wosid | 000262397500022 | - |
dc.identifier.bibliographicCitation | BULLETIN OF THE KOREAN CHEMICAL SOCIETY, v.29, no.12, pp 2413 - 2418 | - |
dc.citation.title | BULLETIN OF THE KOREAN CHEMICAL SOCIETY | - |
dc.citation.volume | 29 | - |
dc.citation.number | 12 | - |
dc.citation.startPage | 2413 | - |
dc.citation.endPage | 2418 | - |
dc.type.docType | Article | - |
dc.identifier.kciid | ART001525804 | - |
dc.description.isOpenAccess | N | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.description.journalRegisteredClass | kci | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.subject.keywordPlus | QUATERNARY NITRIDE | - |
dc.subject.keywordPlus | GERMANIUM NITRIDES | - |
dc.subject.keywordPlus | SILICATE CHEMISTRY | - |
dc.subject.keywordPlus | CRYSTAL-STRUCTURE | - |
dc.subject.keywordPlus | GALLIUM NITRIDES | - |
dc.subject.keywordPlus | GROWING CLASS | - |
dc.subject.keywordPlus | NITRIDOSILICATES | - |
dc.subject.keywordPlus | SUBNITRIDES | - |
dc.subject.keywordAuthor | Barium germanium nitrides | - |
dc.subject.keywordAuthor | Metal nitrides | - |
dc.subject.keywordAuthor | Nitridometallates | - |
dc.identifier.url | https://www.koreascience.or.kr/article/JAKO200802727262526.page | - |
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