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Ba9Ge3N10: A New Ternary Nitride Containing Isolated Planar Triangular Anions of [GeN3](5-)

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dc.contributor.authorPark, Dong Gon-
dc.contributor.authorDiSalvo, Francis J.-
dc.date.available2021-02-22T14:32:17Z-
dc.date.issued2008-12-
dc.identifier.issn0253-2964-
dc.identifier.issn1229-5949-
dc.identifier.urihttps://scholarworks.sookmyung.ac.kr/handle/2020.sw.sookmyung/14113-
dc.description.abstractA new nitride, Ba9Ge3N10, was obtained as single crystals from constituent elements in molten Na. It crystallizes in space group R-3c (No. 167) with a = 7.9399(2) angstrom, c = 17.282(1) angstrom, and Z = 2. It contains the first example of isolated nitridometallate anions of GeN35- in perfect planar triangular shape. Ge-N bond length is 1.786(8) angstrom, which is significantly shorter than any known Ge-N bonds, ranging from 1.84 angstrom to 1.95 angstrom. Valence bond model suggests partial multiple bonding character of the Ge-N bond, which is the first example of such bonding configuration for Ge-N bond. N-centered polyhedral perspective suggests the structure of Ba9Ge3N10 can be conceived as the cationic framework of [Ba9Ge3N9](3+), whose 1/3 of the octahedral interstitial sites are occupied by N3- anions.-
dc.format.extent6-
dc.language영어-
dc.language.isoENG-
dc.publisherKOREAN CHEMICAL SOC-
dc.titleBa9Ge3N10: A New Ternary Nitride Containing Isolated Planar Triangular Anions of [GeN3](5-)-
dc.typeArticle-
dc.publisher.location대한민국-
dc.identifier.doi10.5012/bkcs.2008.29.12.2413-
dc.identifier.scopusid2-s2.0-60149104240-
dc.identifier.wosid000262397500022-
dc.identifier.bibliographicCitationBULLETIN OF THE KOREAN CHEMICAL SOCIETY, v.29, no.12, pp 2413 - 2418-
dc.citation.titleBULLETIN OF THE KOREAN CHEMICAL SOCIETY-
dc.citation.volume29-
dc.citation.number12-
dc.citation.startPage2413-
dc.citation.endPage2418-
dc.type.docTypeArticle-
dc.identifier.kciidART001525804-
dc.description.isOpenAccessN-
dc.description.journalRegisteredClassscie-
dc.description.journalRegisteredClassscopus-
dc.description.journalRegisteredClasskci-
dc.relation.journalResearchAreaChemistry-
dc.relation.journalWebOfScienceCategoryChemistry, Multidisciplinary-
dc.subject.keywordPlusQUATERNARY NITRIDE-
dc.subject.keywordPlusGERMANIUM NITRIDES-
dc.subject.keywordPlusSILICATE CHEMISTRY-
dc.subject.keywordPlusCRYSTAL-STRUCTURE-
dc.subject.keywordPlusGALLIUM NITRIDES-
dc.subject.keywordPlusGROWING CLASS-
dc.subject.keywordPlusNITRIDOSILICATES-
dc.subject.keywordPlusSUBNITRIDES-
dc.subject.keywordAuthorBarium germanium nitrides-
dc.subject.keywordAuthorMetal nitrides-
dc.subject.keywordAuthorNitridometallates-
dc.identifier.urlhttps://www.koreascience.or.kr/article/JAKO200802727262526.page-
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