Detailed Information

Cited 0 time in webofscience Cited 0 time in scopus
Metadata Downloads

Cu2+-induced intermolecular static excimer formation of pyrenealkylamine

Authors
Kim, Hyun JungHong, JooyeonHong, AreumHam, SihyunLee, Joung HaeKim, Jong Seung
Issue Date
May-2008
Publisher
AMER CHEMICAL SOC
Citation
ORGANIC LETTERS, v.10, no.10, pp 1963 - 1966
Pages
4
Journal Title
ORGANIC LETTERS
Volume
10
Number
10
Start Page
1963
End Page
1966
URI
https://scholarworks.sookmyung.ac.kr/handle/2020.sw.sookmyung/14262
DOI
10.1021/ol800475d
ISSN
1523-7060
1523-7052
Abstract
Synthesis of monopyrenylalkylamine derivative 1 and its fluorescence behavior for Cu2+ in H2O/CH3CN (1:1, v/v) were investigated. Upon Cu2+ binding, 1, bearing a sulfonamide group, exhibited a marked excimer emission at 455 nm along with a weak monomer emission at 375 nm. The excimer emission, driven by formation of an intermolecular pyrenyl static excimer upon Cu2+ binding to the sulfonamide group, is rationalized by experimental and theoretical DFT calculation results.
Files in This Item
Go to Link
Appears in
Collections
이과대학 > 화학과 > 1. Journal Articles

qrcode

Items in ScholarWorks are protected by copyright, with all rights reserved, unless otherwise indicated.

Altmetrics

Total Views & Downloads

BROWSE