A mononuclear nonheme manganese(III)-acylperoxo complex: Synthesis, characterization, and reactivity studies
DC Field | Value | Language |
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dc.contributor.author | Jeon, Hyeri | - |
dc.contributor.author | Choi, Seoyeon | - |
dc.contributor.author | Hong, Seungwoo | - |
dc.date.accessioned | 2022-04-19T08:49:17Z | - |
dc.date.available | 2022-04-19T08:49:17Z | - |
dc.date.issued | 2021-11 | - |
dc.identifier.issn | 0253-2964 | - |
dc.identifier.issn | 1229-5949 | - |
dc.identifier.uri | https://scholarworks.sookmyung.ac.kr/handle/2020.sw.sookmyung/146148 | - |
dc.description.abstract | A mononuclear nonheme manganese(III)-acylperoxo complex bearing a simple picolylamine-based linear ligand was synthesized and characterized by various spectroscopic methods along with theoretical calculations. The reactivity of the manganese(III)-acylperoxo complex was investigated in the oxygen atom transfer, C-H and O-H bond activation reactions. The oxidations of organic substrates followed first-order kinetics with respect to substrates and featured nonradical-type, suggesting that the manganese(III)-acylperoxo complex was the reactive oxidant. The C-H bond activation of hydrocarbon and the O-H bond activation of alcohol proceeded via a rate-limiting H-atom abstraction reaction in a concerted manner. | - |
dc.format.extent | 6 | - |
dc.language | 영어 | - |
dc.language.iso | ENG | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.title | A mononuclear nonheme manganese(III)-acylperoxo complex: Synthesis, characterization, and reactivity studies | - |
dc.type | Article | - |
dc.publisher.location | 독일 | - |
dc.identifier.doi | 10.1002/bkcs.12391 | - |
dc.identifier.scopusid | 2-s2.0-85115119806 | - |
dc.identifier.wosid | 000697357200001 | - |
dc.identifier.bibliographicCitation | BULLETIN OF THE KOREAN CHEMICAL SOCIETY, v.42, no.11, pp 1513 - 1518 | - |
dc.citation.title | BULLETIN OF THE KOREAN CHEMICAL SOCIETY | - |
dc.citation.volume | 42 | - |
dc.citation.number | 11 | - |
dc.citation.startPage | 1513 | - |
dc.citation.endPage | 1518 | - |
dc.type.docType | Article | - |
dc.identifier.kciid | ART002778384 | - |
dc.description.isOpenAccess | N | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.description.journalRegisteredClass | kci | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.subject.keywordPlus | 2-HIS-1-CARBOXYLATE FACIAL TRIAD | - |
dc.subject.keywordPlus | META-CHLOROPERBENZOIC ACID | - |
dc.subject.keywordPlus | HYDROGEN-ATOM ABSTRACTION | - |
dc.subject.keywordPlus | ALKANE HYDROXYLATION | - |
dc.subject.keywordPlus | MECHANISTIC INSIGHTS | - |
dc.subject.keywordPlus | DIOXYGEN ACTIVATION | - |
dc.subject.keywordPlus | OLEFIN EPOXIDATION | - |
dc.subject.keywordPlus | IRON ENZYMES | - |
dc.subject.keywordPlus | OXIDATION | - |
dc.subject.keywordPlus | INVOLVEMENT | - |
dc.subject.keywordAuthor | acylperoxo | - |
dc.subject.keywordAuthor | C-H bond activation | - |
dc.subject.keywordAuthor | concerted mechanism | - |
dc.subject.keywordAuthor | phenol oxidation | - |
dc.subject.keywordAuthor | reactive intermediate | - |
dc.identifier.url | https://onlinelibrary.wiley.com/doi/full/10.1002/bkcs.12391 | - |
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