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A mononuclear nonheme manganese(III)-acylperoxo complex: Synthesis, characterization, and reactivity studies

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dc.contributor.authorJeon, Hyeri-
dc.contributor.authorChoi, Seoyeon-
dc.contributor.authorHong, Seungwoo-
dc.date.accessioned2022-04-19T08:49:17Z-
dc.date.available2022-04-19T08:49:17Z-
dc.date.issued2021-11-
dc.identifier.issn0253-2964-
dc.identifier.issn1229-5949-
dc.identifier.urihttps://scholarworks.sookmyung.ac.kr/handle/2020.sw.sookmyung/146148-
dc.description.abstractA mononuclear nonheme manganese(III)-acylperoxo complex bearing a simple picolylamine-based linear ligand was synthesized and characterized by various spectroscopic methods along with theoretical calculations. The reactivity of the manganese(III)-acylperoxo complex was investigated in the oxygen atom transfer, C-H and O-H bond activation reactions. The oxidations of organic substrates followed first-order kinetics with respect to substrates and featured nonradical-type, suggesting that the manganese(III)-acylperoxo complex was the reactive oxidant. The C-H bond activation of hydrocarbon and the O-H bond activation of alcohol proceeded via a rate-limiting H-atom abstraction reaction in a concerted manner.-
dc.format.extent6-
dc.language영어-
dc.language.isoENG-
dc.publisherWILEY-V C H VERLAG GMBH-
dc.titleA mononuclear nonheme manganese(III)-acylperoxo complex: Synthesis, characterization, and reactivity studies-
dc.typeArticle-
dc.publisher.location독일-
dc.identifier.doi10.1002/bkcs.12391-
dc.identifier.scopusid2-s2.0-85115119806-
dc.identifier.wosid000697357200001-
dc.identifier.bibliographicCitationBULLETIN OF THE KOREAN CHEMICAL SOCIETY, v.42, no.11, pp 1513 - 1518-
dc.citation.titleBULLETIN OF THE KOREAN CHEMICAL SOCIETY-
dc.citation.volume42-
dc.citation.number11-
dc.citation.startPage1513-
dc.citation.endPage1518-
dc.type.docTypeArticle-
dc.identifier.kciidART002778384-
dc.description.isOpenAccessN-
dc.description.journalRegisteredClassscie-
dc.description.journalRegisteredClassscopus-
dc.description.journalRegisteredClasskci-
dc.relation.journalResearchAreaChemistry-
dc.relation.journalWebOfScienceCategoryChemistry, Multidisciplinary-
dc.subject.keywordPlus2-HIS-1-CARBOXYLATE FACIAL TRIAD-
dc.subject.keywordPlusMETA-CHLOROPERBENZOIC ACID-
dc.subject.keywordPlusHYDROGEN-ATOM ABSTRACTION-
dc.subject.keywordPlusALKANE HYDROXYLATION-
dc.subject.keywordPlusMECHANISTIC INSIGHTS-
dc.subject.keywordPlusDIOXYGEN ACTIVATION-
dc.subject.keywordPlusOLEFIN EPOXIDATION-
dc.subject.keywordPlusIRON ENZYMES-
dc.subject.keywordPlusOXIDATION-
dc.subject.keywordPlusINVOLVEMENT-
dc.subject.keywordAuthoracylperoxo-
dc.subject.keywordAuthorC-H bond activation-
dc.subject.keywordAuthorconcerted mechanism-
dc.subject.keywordAuthorphenol oxidation-
dc.subject.keywordAuthorreactive intermediate-
dc.identifier.urlhttps://onlinelibrary.wiley.com/doi/full/10.1002/bkcs.12391-
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