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Catechin-Bound Ceanothane-Type Triterpenoid Derivatives from the Roots of Zizyphus jujuba

Authors
Kang, Kyo BinKim, Hyun WooKim, Jung WhaOh, Won KeunKim, JinwoongSung, Sang Hyun
Issue Date
Apr-2017
Publisher
AMER CHEMICAL SOC
Keywords
ZIZIPHUS-JUJUBA; CYCLOPEPTIDE ALKALOIDS; HEPATIC-INJURY; MILL.; FRUIT; PLANT
Citation
JOURNAL OF NATURAL PRODUCTS, v.80, no.4, pp 1048 - 1054
Pages
7
Journal Title
JOURNAL OF NATURAL PRODUCTS
Volume
80
Number
4
Start Page
1048
End Page
1054
URI
https://scholarworks.sookmyung.ac.kr/handle/2020.sw.sookmyung/146994
DOI
10.1021/acs.jnatprod.6b01103
ISSN
0163-3864
1520-6025
Abstract
Three unprecedented ceanothane-type triterpenoids, ent-epicatechinoceanothic acid A (1), ent-epicatechinoceanothic acid B (2), and epicatechino-3-deoxyceanothetric acid A (3), containing C-C bond linkages with catechin moieties, were isolated from the roots of Zizyphus jujuba. Their chemical structures, including absolute configurations, were established by spectroscopic analysis and calculation of their ECD spectra. A possible biogenetic pathway for C-C bond formation between the catechin and the triterpenoid moieties is presented. Compound 1 was evaluated for its antiproliferalive activity on HSC-T6 hepatic stellate cells.
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