Honeycomb-Like Perovskite Oxide Electrocatalyst for a Hybrid Li-Air Battery
- Authors
- Ju, Young-Wan; Yoo, Seonyoung; Guo, Limin; Kim, Changmin; Inoishi, Atsushi; Jeong, Hu Young; Shin, Jeeyoung; Ishihara, Tatsumi; Yim, Sung-Dae; Kim, Guntae
- Issue Date
- Oct-2015
- Publisher
- ELECTROCHEMICAL SOC INC
- Citation
- JOURNAL OF THE ELECTROCHEMICAL SOCIETY, v.162, no.14, pp A2651 - A2655
- Journal Title
- JOURNAL OF THE ELECTROCHEMICAL SOCIETY
- Volume
- 162
- Number
- 14
- Start Page
- A2651
- End Page
- A2655
- URI
- https://scholarworks.sookmyung.ac.kr/handle/2020.sw.sookmyung/147108
- DOI
- 10.1149/2.0311514jes
- ISSN
- 0013-4651
- Abstract
- Honeycomb-like Nd0.7Sr0.3CoO3−δ has been successfully prepared with a PMMA hard-template for an energy storage system and characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), and nitrogen adsorption–desorption measurements. The prepared 3-dimensionally (3-D) ordered mesoporous Nd0.7Sr0.3CoO3−δ (3DOM-NSC) has a well-developed mesoporous structure and has high specific surface area (22.0 m2 g−1). The catalytic activity for the oxygen reduction reaction (ORR) in 0.1 M KOH solution has been studied by using a rotating-ring-disk electrode (RRDE). In the ORR test, a limiting current density of 5.83 mA cm−2 at 0.7 V (vs. Hg/HgO) with 1600 rpm was obtained, a value comparable with that of Pt/C. Moreover, the ORR mainly favors a direct four-electron pathway. Consequently, the high electrocatalytic activity and mesoporous structure result in stable, excellent performance in a hybrid Li-air cell.
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Collections - 공과대학 > 기계시스템학부 > 1. Journal Articles

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