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Mechanistic insight into the hydroxylation of alkanes by a nonheme iron(V)-oxo complex
- Authors
- Kwon, Eunji; Cho, Kyung-Bin; Hong, Seungwoo; Nam, Wonwoo
- Issue Date
- Apr-2014
- Publisher
- ROYAL SOC CHEMISTRY
- Citation
- CHEMICAL COMMUNICATIONS, v.50, no.42, pp 5572 - 5575
- Pages
- 4
- Journal Title
- CHEMICAL COMMUNICATIONS
- Volume
- 50
- Number
- 42
- Start Page
- 5572
- End Page
- 5575
- ISSN
- 1359-7345
1364-548X
- Abstract
- Hydroxylation of alkanes by a mononuclear nonheme iron(V)-oxo complex, [Fe(V)(O)(TAML)](-), is initiated by a rate-determining hydrogen atom(H-atom) abstraction, followed by an oxygen non-rebound process. Evidence for the H-atom abstraction-oxygen non-rebound mechanism is obtained experimentally and supported by DFT calculations.
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