A mononuclear nonheme iron(III)-peroxo complex binding redox-inactive metal ions
DC Field | Value | Language |
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dc.contributor.author | Lee, YM (Lee, Yong-Min) | - |
dc.contributor.author | Bang, S (Bang, Suhee) | - |
dc.contributor.author | Kim, YM (Kim, Yun Mi) | - |
dc.contributor.author | Cho, J (Cho, Jaeheung) | - |
dc.contributor.author | Hong, S (Hong, Seungwoo) | - |
dc.contributor.author | Nomura, T (Nomura, Takashi) | - |
dc.contributor.author | Ogura, T (Ogura, Takashi) | - |
dc.contributor.author | Troeppner, O (Troeppner, Olive | - |
dc.contributor.author | Ivanovic-Burmazovic, I (Ivanov | - |
dc.contributor.author | Sarangi, R (Sarangi, Ritimukta | - |
dc.contributor.author | Fukuzumi, S (Fukuzumi, Shunich | - |
dc.contributor.author | Nam, W (Nam, Wonwoo) | - |
dc.date.accessioned | 2022-04-19T10:22:02Z | - |
dc.date.available | 2022-04-19T10:22:02Z | - |
dc.date.issued | 2013-10 | - |
dc.identifier.issn | 2041-6520 | - |
dc.identifier.issn | 2041-6539 | - |
dc.identifier.uri | https://scholarworks.sookmyung.ac.kr/handle/2020.sw.sookmyung/147521 | - |
dc.description.abstract | Redox-inactive metal ions that function as Lewis acids play pivotal roles in modulating reactivities of oxygen-containing metal complexes in a variety of biological and biomimetic reactions, including dioxygen activation/formation and functionalization of organic substrates. Mononuclear nonheme iron(III)-peroxo species are invoked as active oxygen intermediates in the catalytic cycles of dioxygen activation by nonheme iron enzymes and their biomimetic compounds. Here, we report mononuclear nonheme iron(III)-peroxo complexes binding redox-inactive metal ions, [(TMC)Fe-III(O-2)]+-M3+ (M3+ Sc3+ and Y3+; TMC = 1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecane), which are characterized spectroscopically as a 'side-on' iron(III)-peroxo complex binding a redox-inactive metal ion, (TMC) Fe-III(mu,eta(2):eta(2)-O-2)-M3+ (2-M). While an iron(III)-peroxo complex, [(TMC) Fe-III(O-2)](+), does not react with electron donors (e.g., ferrocene), one-electron reduction of the iron(III)-peroxo complexes binding redox-inactive metal ions occurs readily upon addition of electron donors, resulting in the generation of an iron(IV)oxo complex, [(TMC) FeIV(O)](2+) (4), via heterolytic O-O bond cleavage of the peroxide ligand. The rates of the conversion of 2-M to 4 are found to depend on the Lewis acidity of the redox-inactive met | - |
dc.format.extent | 7 | - |
dc.language | 영어 | - |
dc.language.iso | ENG | - |
dc.publisher | ROYAL SOC CHEMISTRY | - |
dc.title | A mononuclear nonheme iron(III)-peroxo complex binding redox-inactive metal ions | - |
dc.type | Article | - |
dc.publisher.location | 영국 | - |
dc.identifier.doi | 10.1039/c3sc51864g | - |
dc.identifier.scopusid | 2-s2.0-84883308619 | - |
dc.identifier.wosid | 000323843500019 | - |
dc.identifier.bibliographicCitation | CHEMICAL SCIENCE, v.4, no.10, pp 3917 - 3923 | - |
dc.citation.title | CHEMICAL SCIENCE | - |
dc.citation.volume | 4 | - |
dc.citation.number | 10 | - |
dc.citation.startPage | 3917 | - |
dc.citation.endPage | 3923 | - |
dc.description.isOpenAccess | N | - |
dc.description.journalRegisteredClass | sci | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
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