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Metal-organic frameworks for visible light absorption via anion substitution

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dc.contributor.authorChoi, Jung Hoon-
dc.contributor.authorJeon, Hyung Joon-
dc.contributor.authorChoi, Kyung Min-
dc.contributor.authorKang, Jeung Ku-
dc.date.accessioned2022-04-19T10:26:08Z-
dc.date.available2022-04-19T10:26:08Z-
dc.date.issued2012-05-
dc.identifier.issn0959-9428-
dc.identifier.issn1364-5501-
dc.identifier.urihttps://scholarworks.sookmyung.ac.kr/handle/2020.sw.sookmyung/147667-
dc.description.abstractWe report that the band gap of metal-organic frameworks (MOFs) could be tuned to absorb visible light via anion substitution. First of all, when an oxygen anion in the metal oxide core of IRMOF-1 is substituted with sulphur anions as Zn4S or selenium anions as Zn4Se to form IRMOF-1-S and IRMOF-1-Se, respectively, they result in density-of-states and molecular orbitals for the band gap that can utilize visible light through shifting of the Fermi level due to their electron-rich properties. This implies that the tailored band gap could provide a new route to allow the series of IRMOFs and other MOFs to be used for visible light absorption.-
dc.format.extent4-
dc.language영어-
dc.language.isoENG-
dc.publisherROYAL SOC CHEMISTRY-
dc.titleMetal-organic frameworks for visible light absorption via anion substitution-
dc.typeArticle-
dc.publisher.location영국-
dc.identifier.doi10.1039/c2jm16245h-
dc.identifier.scopusid2-s2.0-84860463070-
dc.identifier.wosid000303442300006-
dc.identifier.bibliographicCitationJOURNAL OF MATERIALS CHEMISTRY, v.22, no.20, pp 10144 - 10147-
dc.citation.titleJOURNAL OF MATERIALS CHEMISTRY-
dc.citation.volume22-
dc.citation.number20-
dc.citation.startPage10144-
dc.citation.endPage10147-
dc.description.isOpenAccessN-
dc.description.journalRegisteredClassscie-
dc.description.journalRegisteredClassscopus-
dc.identifier.urlhttps://pubs.rsc.org/en/content/articlelanding/2012/JM/c2jm16245h-
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