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Picolyl armed C-1,2 alternate tetrahomodioxacalix[4]arene tetraamides
- Issue Date
- Dec-2003
- Publisher
- SPRINGER
- Keywords
- calixarene; homooxacalixarene; complexation; X-ray crystal structure
- Citation
- JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY, v.47, no.3-4, pp 167 - 171
- Pages
- 5
- Journal Title
- JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY
- Volume
- 47
- Number
- 3-4
- Start Page
- 167
- End Page
- 171
- ISSN
- 1388-3127
1573-1111
- Abstract
- A series of benzyl, 2-picolyl, 3-picolyl armed tetrahomodioxacalix[4] arene tetraamides with four p-phenyl groups on the upper rim were synthesized. They were found to be in the C-1,2-alternate conformation by H-1, C-13 NMR, and X-ray crystal structure. The nitrogen atom of the 2-picolyl group played an important role in the metal ion complexation.
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