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cis-bis(alkenyl)iridium(III) compounds by apparent insertion of two acetylenes into two Ir-P bonds: Crystal structures of cis,trans-[IrCl(-CH = CH+PPh3)(2)(CO)(PPh3)(2)](2+) and [Ir(OClO3)(CH3)(H2O)(CO)(PPh3)(2)](+)

Authors
Chin, CSLee, MOh, MWon, GKim, MPark, YJ
Issue Date
17-Apr-2000
Publisher
AMER CHEMICAL SOC
Citation
ORGANOMETALLICS, v.19, no.8, pp.1572 - 1577
Journal Title
ORGANOMETALLICS
Volume
19
Number
8
Start Page
1572
End Page
1577
URI
https://scholarworks.sookmyung.ac.kr/handle/2020.sw.sookmyung/16771
DOI
10.1021/om0000459
ISSN
0276-7333
Abstract
cis-Bis(alkenyl)iridium complexes cis,trans-[IrR(-CH=CH+PPh3)(2)(CO)(PPh3)(2)](2+) (2, R = H (a), CH3 (b), Cl (c)) have been prepared from the reactions of dihaloiridium(III) compounds with HC=CR and PPh3. Reactions of 2b and 2c with CH2=CHCH2Br give bis(alkenyl)(PPh3)iridium, cis-[IrBr(CH3)(-CH=CH+PPh3)(2)(CO)(PPh3)](+), and cis,cis[IrBr2(-CH=CH-+PPh3)(2)(CO)(PPh3)](+). Crystal structures of 2c and [Ir(OClO3)(CH3)(H2O)(CO)(PPh3)(2)](+) (4) have been determined by X-ray diffraction data analysis.
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