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Bidentate chelation-controlled asymmetric synthesis of alpha-hydroxy esters based on the glycolate enolate alkylation

Authors
Jung, JEHo, HKim, HD
Issue Date
11-Mar-2000
Publisher
PERGAMON-ELSEVIER SCIENCE LTD
Keywords
asymmetric synthesis; chelation; hydroxy acid and derivatives; alkylation
Citation
TETRAHEDRON LETTERS, v.41, no.11, pp.1793 - 1796
Journal Title
TETRAHEDRON LETTERS
Volume
41
Number
11
Start Page
1793
End Page
1796
URI
https://scholarworks.sookmyung.ac.kr/handle/2020.sw.sookmyung/16778
DOI
10.1016/S0040-4039(00)00031-9
ISSN
0040-4039
Abstract
(S)- [(4R)-2,2-Dimethyl- 1,3-dioxolan-4-yl] (4-methoxyphenyl)methanol (4b) has been synthesized and evaluated as a chiral auxiliary for the asymmetric synthesis of cx-hydroxy esters based on bidentate chelation-controlled alkylation of glycolate enolate. (C) 2000 Elsevier Science Ltd. All rights reserved.
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