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Achieving One-Electron Oxidation of a Mononuclear Nonheme Iron(V)-Imido Complex
- Authors
- Hong, Seungwoo; Lu, Xiaoyan; Lee, Yong-Min; Seo, Mi Sook; Ohta, Takehiro; Ogura, Takashi; Clemancey, Martin; Maldivi, Pascale; Latour, Jean-Marc; Sarangi, Ritimukta; Nam, Wonwoo
- Issue Date
- Oct-2017
- Publisher
- AMER CHEMICAL SOC
- Citation
- JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, v.139, no.41, pp 14372 - 14375
- Pages
- 4
- Journal Title
- JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Volume
- 139
- Number
- 41
- Start Page
- 14372
- End Page
- 14375
- ISSN
- 0002-7863
1520-5126
- Abstract
- A mononuclear nonheme iron(V)-imido complex, earing a tetraamido macrocyclic ligand (TAML), [Fe-V(NTs)(TAIVIL)](-) (1), was oxidized by one-electron oxidants, affording formation,of an iron(V)-imido TAML cation radical species; [Fe-V(NTs)(TAML(+.))] (2); 2 is a diamagnetic (S = 0) complex, resulting froni the antiferroinagnetic coupling of the low-spin iron(V) ion (S = 1/2) with the one-electron oxidized ligand (TAML(+)). 2 is a competent oxidant in C-H bond functionalization and riltrene transfer reaction, showing that the reactivity of 2 is greater than that of 1.
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