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A Mononuclear Nonheme Iron(V)-Imido Complex

Authors
Hong, SeungwooSutherlin, Kyle D.Vardhaman, Anil KumarYan, James J.Park, SoraLee, Yong-MinJang, SoojeongLu, XiaoyanOhta, TakehiroOgura, TakashiSolomon, Edward I.Nam, Wonwoo
Issue Date
Jul-2017
Publisher
AMER CHEMICAL SOC
Citation
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, v.139, no.26, pp 8800 - 8803
Pages
4
Journal Title
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume
139
Number
26
Start Page
8800
End Page
8803
URI
https://scholarworks.sookmyung.ac.kr/handle/2020.sw.sookmyung/8249
DOI
10.1021/jacs.7b04695
ISSN
0002-7863
1520-5126
Abstract
Mononuclear nonheme iron(V)-oxo complexes have been reported previously. Herein, we report the first example of a mononuclear nonheme iron(V)-imido complex bearing a tetraamido macrocyclic ligand (TAML), [(TAML)Fe-V(NTs)](-) (1). The spectroscopic characterization of 1 revealed an S = 1/2 Fe(V) oxidation state, an Fe-N bond length of 1.65(4) angstrom, and an Fe-N vibration at 817 cm(-1). The reactivity of 1 was demonstrated in C-H bond functionalization and nitrene transfer reactions.
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