A Mononuclear Nonheme Iron(V)-Imido Complex
- Authors
- Hong, Seungwoo; Sutherlin, Kyle D.; Vardhaman, Anil Kumar; Yan, James J.; Park, Sora; Lee, Yong-Min; Jang, Soojeong; Lu, Xiaoyan; Ohta, Takehiro; Ogura, Takashi; Solomon, Edward I.; Nam, Wonwoo
- Issue Date
- Jul-2017
- Publisher
- AMER CHEMICAL SOC
- Citation
- JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, v.139, no.26, pp 8800 - 8803
- Pages
- 4
- Journal Title
- JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Volume
- 139
- Number
- 26
- Start Page
- 8800
- End Page
- 8803
- URI
- https://scholarworks.sookmyung.ac.kr/handle/2020.sw.sookmyung/8249
- DOI
- 10.1021/jacs.7b04695
- ISSN
- 0002-7863
1520-5126
- Abstract
- Mononuclear nonheme iron(V)-oxo complexes have been reported previously. Herein, we report the first example of a mononuclear nonheme iron(V)-imido complex bearing a tetraamido macrocyclic ligand (TAML), [(TAML)Fe-V(NTs)](-) (1). The spectroscopic characterization of 1 revealed an S = 1/2 Fe(V) oxidation state, an Fe-N bond length of 1.65(4) angstrom, and an Fe-N vibration at 817 cm(-1). The reactivity of 1 was demonstrated in C-H bond functionalization and nitrene transfer reactions.
- Files in This Item
-
Go to Link
- Appears in
Collections - 이과대학 > 화학과 > 1. Journal Articles
Items in ScholarWorks are protected by copyright, with all rights reserved, unless otherwise indicated.