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Redox- and pH-Responsive Orthogonal Supramolecular Self-Assembly: An Ensemble Displaying Molecular Switching Characteristics
- Kim, Dong Sub;
- Chang, Jinho;
- Leem, Soojung;
- Park, Jung Su;
- Thordarson, Pall;
- 외 1명
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83초록
Two heteroditopic monomers, namely a thiopropyl-functionalized tetrathiafulvalene-annulated calix[4]pyrrole (SPr-TTF-C[4]P1) and phenyl C-61 butyric acid (PCBA 2), have been used to assemble a chemically and electrochemically responsive supramolecular ensemble. Addition of an organic base initiates self-assembly of the monomers via a molecular switching event. This results in the formation of materials that may be disaggregated via the addition of an organic acid or electrolysis.
키워드
POLYMERS; COPOLYMERS; TETRATHIAFULVALENES; DERIVATIVES; COMPLEXES; SCAFFOLDS; CHEMISTRY; BINDING
- 제목
- Redox- and pH-Responsive Orthogonal Supramolecular Self-Assembly: An Ensemble Displaying Molecular Switching Characteristics
- 저자
- Kim, Dong Sub; Chang, Jinho; Leem, Soojung; Park, Jung Su; Thordarson, Pall; Sessler, Jonathan L.
- 발행일
- 2015-12
- 유형
- Article
- 권
- 137
- 호
- 51
- 페이지
- 16038 ~ 16042
- 언어
- ENG
- 출판사
- AMER CHEMICAL SOC
- 발행국가
- 미국
- 분량
- 5 페이지
- ISSN
- E 1520-5126
P 0002-7863