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초록
We report the synthesis of an end-on dinuclear Mn(ii) azide complex with two bridging azide ligands that served as a precursor for the formation of an end-on bis(mu-hydroxido) dinuclear Mn(ii,iii) azide complex upon oxidation by organic peroxide or peracids. Combined experimental and theoretical studies on the reactivity of the end-on bis(mu-hydroxido) dinuclear Mn(ii,iii) azide complex suggest that the reaction with substrates having weak C-H bond and O-H bond dissociation energy occurred via a H-atom abstraction reaction in a concerted manner.
키워드
HYDROGEN-ATOM ABSTRACTION; MANGANESE-LIPOXYGENASE; STRUCTURAL-CHARACTERIZATION; MECHANISTIC INSIGHTS; OXIDATION; MN
- 제목
- An end-on bis(mu-hydroxido) dimanganese(ii,iii) azide complex for C-H bond and O-H bond activation reactions
- 저자
- Jeon, Hyeri; Kim, Jisoo; Kim, Jin; Cho, Kyung-Bin; Hong, Seungwoo
- 발행일
- 2022-04
- 유형
- Article
- 권
- 58
- 호
- 29
- 페이지
- 4623 ~ 4626