Concentration of docosahexsaenoic acid from tuna oil by a combination of solvent crystallization and lipase-catalyzed ethanolysis
  • Park, Mi Soon
  • Wee, Chido
  • Lee, Junsoo
  • Kim, Byung Hee
  • Kim, Hak-Ryul
  • 외 1명
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초록

The docosahexaenoic acid (DHA) was concentrated from tuna oil fatty acid using solvent crystallization combined with lipase-catalyzed ethanolysis. In the first step, solvent crystallization was carried out to concentrate DHA from tuna oil fatty acid using acetonitrile as a solvent. The optimal conditions of solvent crystallization were the crystallization temperature of -40 degrees C and the fatty acid to solvent ratio of 1:8 (w/v). This step increased the DHA content in the original tuna oil fatty acid from 22% up to 61%. In the second step, lipase-catalyzed ethanolysis was conducted with DHA-enriched fatty acid from the first step using Lipozyme RM IM (from Rhizomucor miehei) as a biocatalyst. The optimum conditions of this second step were the reaction temperature of 20 degrees C and the molar ratio of 1:1 (fatty acid to ethanol). Overall, DHA enrichment with purity of 85% was obtained by the two step processes.

키워드

docosahexaenoic acidenrichmentethanolysislipaseLipozyme RM IMsolvent crystallizationDOCOSAHEXAENOIC ACIDFATTY-ACIDSFISH-OILSELECTIVE ESTERIFICATIONENZYMATIC ESTERIFICATIONEICOSAPENTAENOIC ACIDSTEARIDONIC ACIDECHIUM OILENRICHMENTDHA
제목
Concentration of docosahexsaenoic acid from tuna oil by a combination of solvent crystallization and lipase-catalyzed ethanolysis
저자
Park, Mi SoonWee, ChidoLee, JunsooKim, Byung HeeKim, Hak-RyulKim, In-Hwan
DOI
10.1002/aocs.12817
발행일
2024-07
유형
Article; Early Access
저널명
JAOCS, Journal of the American Oil Chemists' Society
101
7
페이지
637 ~ 645