Pd(ii)-catalyzed direct C-H acylation of N-Boc hydrazones with aldehydes: One-pot synthesis of 1,2-diacylbenzenes

  • Sharma, Satyasheel; 
  • Kim, Aejin; 
  • Park, Jihye; 
  • Kim, Mirim; 
  • Kwak, Jong Hwan; 
  • ... Park, Jung Su; 
  • 외 2명
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초록

A palladium(ii)-catalyzed direct acylation of acetophenone N-Boc hydrazones with aldehydes via C-H bond activation is described. This protocol provides direct access to a range of 1,2-diacylbenzenes, which are useful precursors to construct biologically interesting and pharmaceutically important compounds. © 2013 The Royal Society of Chemistry.

키워드

Acetophenones; CH-bond activation; Hydrazones; One-pot synthesis; Acylation; Aldehydes; Catalysis; Ketones; Palladium compounds; aldehyde; benzophenone derivative; hydrazone derivative; organometallic compound; palladium; acylation; article; catalysis; chemical structure; chemistry; synthesis; Acylation; Aldehydes; Benzophenones; Catalysis; Hydrazones; Molecular Structure; Organometallic Compounds; Palladium
제목
Pd(ii)-catalyzed direct C-H acylation of N-Boc hydrazones with aldehydes: One-pot synthesis of 1,2-diacylbenzenes
저자
Sharma, Satyasheel; Kim, Aejin; Park, Jihye; Kim, Mirim; Kwak, Jong Hwan; Jung, Young Hoon; Park, Jung Su; Kim, In Su
DOI
10.1039/c3ob41644e
발행일
2013-12
유형
Article
저널명
Organic & Biomolecular Chemistry
권
11
호
45
페이지
7869 ~ 7876