Synthesis and structure of Li4Sr3Ge2N6: a new quaternary nitride containing Ge2N610- anions

Park, DG; Gal, ZA; DiSalvo, FJ

doi:10.1016/S0022-4596(03)00009-4

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Synthesis and structure of Li4Sr3Ge2N6: a new quaternary nitride containing Ge2N610- anions

Park, DG;
Gal, ZA;
DiSalvo, FJ

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WEB OF SCIENCE

30

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SCOPUS

32

초록

A new Li-containing quaternary nitride, Li4Sr3Ge2N6, was obtained as single crystals from constituent elements in molten Na. It crystallizes in space group C2/m (No. 12) with a = 6.1398(7) Angstrom b = 10.021(1) Angstrom, c = 6.3130(7) Angstrom, beta = 91.279(2)degrees, and Z = 2. It contains the first example of isolated nitridogermanate anions of Ge2N610-, which is also the first example of edge-sharing tetrahedral [GeN4]. (C) 2003 Elsevier Science (USA). All rights reserved.

키워드

CRYSTAL-STRUCTURE; SILICATE CHEMISTRY; GERMANIUM NITRIDES; METAL NITRIDES; GROWING CLASS; TERNARY; NITRIDOSILICATES; SUBNITRIDES

제목: Synthesis and structure of Li4Sr3Ge2N6: a new quaternary nitride containing Ge2N610- anions

저자: Park, DG; Gal, ZA; DiSalvo, FJ

DOI: 10.1016/S0022-4596(03)00009-4

발행일: 2003-04

유형: Article

저널명: Journal of Solid State Chemistry

권: 172

호: 1

페이지: 166 ~ 170