Adsorption of Acetonitrile on Si(111)-(7 x 7)
  • Hong, Suklyun
  • Min, Kyung-Ah
  • Park, Jinwoo
  • Kim, Hanchul
  • Mizutani, Hironori
  • 외 1명
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초록

The adsorption of acetonitrile (CH3CN) on Si(111)-(7 x 7) at a room temperature has been investigated using scanning tunneling microscopy (STM) and first-principles calculations. The site-specific information on adsorption enables us to understand the site-by-site and step-by-step adsorption mechanism. From theoretical simulations, the most stable configuration of CH3CN on Si(111)-(7 x 7) is found to be a molecularly chemisorbed CH3CN with the carbon and nitrogen atoms of CN bonded to the rest atom and adatom on the Si surface, respectively. Some chemisorption-induced features in the STM topographic image are assigned based on the theoretical calculations.

제목
Adsorption of Acetonitrile on Si(111)-(7 x 7)
저자
Hong, SuklyunMin, Kyung-AhPark, JinwooKim, HanchulMizutani, HironoriOkada, Michio
DOI
10.1021/acsomega.0c01445
발행일
2020-09
저널명
ACS OMEGA
5
38
페이지
24179 ~ 24185