ScholarWorks@숙명여자대학교

초록

During the past several decades, considerable effort has focused on self-assembled systems. However, most work has been directed toward understanding the equilibrium between two major chemical entities, namely the dissociated components and the corresponding associated complex. While there are quite a few examples of multiresponsive materials, control over multistate materials has proved difficult to achieve. Here, we report the formation and the interplay of a self-assembled calix[4]pyrrole array that exhibits three limiting forms, namely a 1:1 self-assembled oligomer, a 2:1 capsule, and the corresponding monomers. Interconversion between these states may be controlled by using the tetraethylammonium cation (TEA(+)) and/or iodide anion (I ) as chemical inputs. The combination of self-assembly and ion-based control may be used to create systems that display NAND logic behavior. The system outputs have been confirmed by a variety of analytic methods, including UVvis and 2D H-1 DOSY, NOESY NMR spectroscopy, scanning electron microscopy, and single crystal X-ray diffraction analyses.

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