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초록
Solvent-, acidity-, and redox-responsive thione(thiol)-disulfide interconversion were achieved by a dinuclear copper(ii) complex bearing a bis(thiosemicarbazone) (bTSC) ligand. The role of copper(ii) ion coordination was rationalized by parallel comparison with a bare bTSC ligand and zinc(ii) bTSC complexes under identical reaction conditions.
키워드
DYNAMIC COMBINATORIAL CHEMISTRY; CHELATING-AGENTS; GLUTATHIONE; ELECTROCHEMISTRY; PENICILLAMINE; LIBRARIES; OXIDATION; DNA
- 제목
- Factors that determine thione( thiol)- disulfide interconversion in a bis( thiosemicarbazone) copper( II) complex
- 저자
- Jeong, Haewon; Kang, Yeji; Kim, Jin; Kim, Byung-Kwon; Hong, Seungwoo
- 발행일
- 2019-03
- 유형
- Article
- 저널명
- RSC Advances
- 권
- 9
- 호
- 16
- 페이지
- 9049 ~ 9052