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Dual Role of Anthranils as Amination and Transient Directing Group Sources: Synthesis of 2-Acyl Acridines
- Kim, Saegun;
- Han, Sang Hoon;
- Mishra, Neeraj Kumar;
- Chun, Rina;
- Jung, Young Hoon;
- ... Park, Jung Su;
- 외 2명
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The transient directing group promoted C-(sp(2))-H functionalization of benzaldehydes with anthranils by a cationic rhodium(III) catalyst is described. Notably, anthranils have been used as both transient directing groups and amination sources to afford 2-aryl acridines through direct C-H amination followed by acid-mediated cyclization. A range of substrate scopes and functional group tolerance were observed.
키워드
C-H AMINATION; UNSYMMETRICAL ACRIDINES; AROMATIC KETONES; BOND; FUNCTIONALIZATION; BENZALDEHYDES; CYCLIZATION; ALKYLATION; AMIDATION; ALDEHYDES
- 제목
- Dual Role of Anthranils as Amination and Transient Directing Group Sources: Synthesis of 2-Acyl Acridines
- 저자
- Kim, Saegun; Han, Sang Hoon; Mishra, Neeraj Kumar; Chun, Rina; Jung, Young Hoon; Kim, Hyung Sik; Park, Jung Su; Kim, In Su
- 발행일
- 2018-07
- 유형
- Article
- 저널명
- Organic Letters
- 권
- 20
- 호
- 13
- 페이지
- 4010 ~ 4014
- 언어
- ENG
- 출판사
- AMER CHEMICAL SOC
- 발행국가
- 미국
- 분량
- 5 페이지
- ISSN
- E 1523-7052
P 1523-7060