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초록
Mononuclear nonheme iron(V)-oxo complexes have been reported previously. Herein, we report the first example of a mononuclear nonheme iron(V)-imido complex bearing a tetraamido macrocyclic ligand (TAML), [(TAML)Fe-V(NTs)](-) (1). The spectroscopic characterization of 1 revealed an S = 1/2 Fe(V) oxidation state, an Fe-N bond length of 1.65(4) angstrom, and an Fe-N vibration at 817 cm(-1). The reactivity of 1 was demonstrated in C-H bond functionalization and nitrene transfer reactions.
키워드
METAL-OXO COMPLEXES; OXIDATION REACTIONS; TRANSFER REACTIVITY; IRON; IRON(IV)-OXO; NITRIDO; FE; HYDROXYLATION; ENVIRONMENTS; AMINATION
- 제목
- A Mononuclear Nonheme Iron(V)-Imido Complex
- 저자
- Hong, Seungwoo; Sutherlin, Kyle D.; Vardhaman, Anil Kumar; Yan, James J.; Park, Sora; Lee, Yong-Min; Jang, Soojeong; Lu, Xiaoyan; Ohta, Takehiro; Ogura, Takashi; Solomon, Edward I.; Nam, Wonwoo
- 발행일
- 2017-07
- 유형
- Article
- 권
- 139
- 호
- 26
- 페이지
- 8800 ~ 8803
- 언어
- ENG
- 출판사
- AMER CHEMICAL SOC
- 발행국가
- 미국
- 분량
- 4 페이지
- ISSN
- E 1520-5126
P 0002-7863