Network of Heterogeneous Catalyst Arrays on the Nitrogen-Doped Graphene for Synergistic Solar Energy Harvesting of Hydrogen from Water
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초록

Combination of different nanoparticles has been suggested as a promising approach to realize advanced functionalities for many applications. Herein, we report a new method to make uniform sized nanoparticle arrays in a network by arranging a micelle monolayer in an ordered fashion on the conductive nitrogen-doped graphene (NG). Moreover, coarrangement of two different arrays using both metal and metal oxide nanoparticles on the conductive graphene is found to result in the synergistic and cooperative photocatalytic activity for production of hydrogen from water using solar energy, with the excellent performance attributed to efficient electron transfer from one nanoparticle through the conductive NG to the other nanoparticle in a single-layer network. Consequently, this work suggests a promising solution to design high-performance catalysts in a network of different nanoparticle arrays on thin and flexible conductive substrates.

키워드

OXIDEPERFORMANCESEMICONDUCTORPHOTOCATALYSTNANOPARTICLESNANOCOMPOSITESGENERATIONCONVERSIONPARTICLESLAYERS
제목
Network of Heterogeneous Catalyst Arrays on the Nitrogen-Doped Graphene for Synergistic Solar Energy Harvesting of Hydrogen from Water
저자
Shin, Sang RimPark, Jung HyoKim, Keon-HanChoi, Kyung MinKang, Jeung Ku
DOI
10.1021/acs.chemmater.6b02780
발행일
2016-11
유형
Article
저널명
Chemistry of Materials
28
21
페이지
7725 ~ 7730