Enhancement of Catalytic Activity of Reduced Graphene Oxide Via Transition Metal Doping Strategy
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초록

To compare the catalytic oxidation activities of reduced graphene oxide (rGO) and rGO samples doped with five different transition metals (TM-rGO), we determine their effects on the oxidation of L-cysteine (Cys) in aqueous solution by performing electrochemistry (EC) measurements and on the photocatalytic oxidation of Cys by using high-resolution photoemission spectroscopy (HRPES) under UV illumination. Our results show that Cr-, Fe-, and Co-doped rGO with 3+ charge states (stable oxide forms: Cr3+, Fe3+, and Co3+) exhibit enhanced catalytic activities that are due to the charge states of the doped metal ions as we compare them with Cr-, Fe-, and Co-doped rGO with 2+ charge states.

키워드

Catalytic oxidationTransition metal-doped rGOHRPESSEMElectrochemical measurementVISIBLE-LIGHT IRRADIATIONHYDROGEN-PRODUCTIONION BATTERIESXPSPHOTOCATALYSTSNANOCOMPOSITESPERFORMANCECOMPOSITESMORPHOLOGYOXIDATION
제목
Enhancement of Catalytic Activity of Reduced Graphene Oxide Via Transition Metal Doping Strategy
저자
Lee, HangilHong, Jung A.
DOI
10.1186/s11671-017-2196-4
발행일
2017-06
유형
Article
저널명
Nanoscale Research Letters
12