Palladium Induced Macrocyclic Preorganization for Stabilization of a Tetrathiafulvalene Mixed-Valence Dimer

  • Bejger, Christopher
  • Davis, Christina M.
  • Park, Jung Su
  • Lynch, Vincent M.
  • Love, Jason B.
  • 외 1명
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초록

Ditopic metalation of a flexible Pacman-like tetrathiafulvalene (TTF) modified Schiff-base-calixpyrrole results in the stabilization upon oxidation of an otherwise difficult-to-access mixed-valence TTF radical dimer. EPR and optical spectroscopies were used to characterize the mixed-valence species.

제목
Palladium Induced Macrocyclic Preorganization for Stabilization of a Tetrathiafulvalene Mixed-Valence Dimer
저자
Bejger, ChristopherDavis, Christina M.Park, Jung SuLynch, Vincent M.Love, Jason B.Sessler, Jonathan L.
DOI
10.1021/ol201992x
발행일
2011-09
저널명
Organic Letters
13
18
페이지
4902 ~ 4905