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Microwave spectrum of 4-ethylcyclohexanone

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dc.contributor.authorKa, Soohyun-
dc.contributor.authorPark, Inhee-
dc.contributor.authorOh, Jung Jin-
dc.date.available2021-02-22T14:33:05Z-
dc.date.issued2008-09-
dc.identifier.issn0022-2852-
dc.identifier.issn1096-083X-
dc.identifier.urihttps://scholarworks.sookmyung.ac.kr/handle/2020.sw.sookmyung/14195-
dc.description.abstractThe rotational spectrum of 4-ethylcyclohexanone in the ground vibrational state has been observed in the frequency region from 6.0 to 18.0 GHz. Transitions having a-, b-, and c-dipole selection rules were all seen. The rotational constants are A = 3660.3669(20), B = 931.6707(3) and C = 796.8889(3)MHz. The elec tric dipole moment was also measured to give vertical bar mu(a)vertical bar = 3.111(2)D, vertical bar mu(b)vertical bar = 0.481(6) D, vertical bar mu(c)vertical bar = 1.059(2) D, vertical bar mu(tot)vertical bar = 3.321(13) D. These rotational parameters are consistent chair conformation with the equatorial ethyl group and the terminal carbon staggering between the hydrogen and carbon. (C) 2008 Elsevier Inc. All rights reserved.-
dc.format.extent4-
dc.language영어-
dc.language.isoENG-
dc.publisherACADEMIC PRESS INC ELSEVIER SCIENCE-
dc.titleMicrowave spectrum of 4-ethylcyclohexanone-
dc.typeArticle-
dc.publisher.location미국-
dc.identifier.doi10.1016/j.jms.2008.04.008-
dc.identifier.scopusid2-s2.0-50149096794-
dc.identifier.wosid000259167900047-
dc.identifier.bibliographicCitationJOURNAL OF MOLECULAR SPECTROSCOPY, v.251, no.1-2, pp 374 - 377-
dc.citation.titleJOURNAL OF MOLECULAR SPECTROSCOPY-
dc.citation.volume251-
dc.citation.number1-2-
dc.citation.startPage374-
dc.citation.endPage377-
dc.type.docTypeArticle-
dc.description.isOpenAccessN-
dc.description.journalRegisteredClassscie-
dc.description.journalRegisteredClassscopus-
dc.relation.journalResearchAreaPhysics-
dc.relation.journalResearchAreaSpectroscopy-
dc.relation.journalWebOfScienceCategoryPhysics, Atomic, Molecular & Chemical-
dc.relation.journalWebOfScienceCategorySpectroscopy-
dc.subject.keywordPlusMULTIPHOTON IONIZATION SPECTROSCOPY-
dc.subject.keywordPlusELECTRON-DIFFRACTION-
dc.subject.keywordPlusDIPOLE-MOMENT-
dc.subject.keywordPlusCYCLOHEXANONE-
dc.subject.keywordPlus2-METHYLCYCLOHEXANONE-
dc.subject.keywordPlusCONFORMATION-
dc.subject.keywordPlusARGON-
dc.subject.keywordAuthor4-ethylcyclohexanone-
dc.subject.keywordAuthorrotational spectrum-
dc.subject.keywordAuthormicrowave-
dc.subject.keywordAuthordipole selection rules-
dc.subject.keywordAuthorchair conformation-
dc.subject.keywordAuthorequatorial group-
dc.subject.keywordAuthoraxial conformer-
dc.subject.keywordAuthorAb initio-
dc.identifier.urlhttps://www.sciencedirect.com/science/article/abs/pii/S0022285208001471?via%3Dihub-
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