Acetylene Gas Mediated Conjugated Microporous Polymers (ACMPs): First Use of Acetylene Gas as a Building Unit
DC Field | Value | Language |
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dc.contributor.author | Choi, JH (Choi, Jung Hoon) | - |
dc.contributor.author | Choi, KM (Choi, Kyung Min) | - |
dc.contributor.author | Jeon, HJ (Jeon, Hyung Joon) | - |
dc.contributor.author | Choi, YJ (Choi, Yoon Jeong) | - |
dc.contributor.author | Lee, Y (Lee, Yeob) | - |
dc.contributor.author | Kang, JK (Kang, Jeung Ku) | - |
dc.date.accessioned | 2022-04-19T10:44:05Z | - |
dc.date.available | 2022-04-19T10:44:05Z | - |
dc.date.issued | 2010-07 | - |
dc.identifier.issn | 0024-9297 | - |
dc.identifier.issn | 1520-5835 | - |
dc.identifier.uri | https://scholarworks.sookmyung.ac.kr/handle/2020.sw.sookmyung/147904 | - |
dc.description.abstract | The facile method to synthesize microporous nanostructure acetylene mediated conjugated microporous polymers (ACMPs) with functional linkers through the one step Sonogashira reaction was reported. ACMP-C was fabricated by linking tetrakis(4-iodophenyl) methane with an acetylene gas, whereas ACMP-C6 and ACMP-N were synthesized from 1,3,5-tris(4-iodophenyl)benzene and tris(4-iodophenyl)amine, respectively. ACMP-C6 was synthesized using a planar-type starting building unit with three iodine terminals less suitable for formation of 3-dimensional networked nanostructure. The SEM analysis shows that the morphologies of the ACMPs are based on the structures assembled by only the sphere phase with 10-100 nm scale sizes. A thermal gravimetric analysis reveals that the ACMPs are stable up to 300°C and that the maximum weight loss occurs at the temperatures above 500°C. The results show that the ACMPs are stable in water and in general organic solvents such as chloroform, THF, acetone, methanol, hexane, and N,N-dimethylformamide. | - |
dc.format.extent | 4 | - |
dc.language | 영어 | - |
dc.language.iso | ENG | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | Acetylene Gas Mediated Conjugated Microporous Polymers (ACMPs): First Use of Acetylene Gas as a Building Unit | - |
dc.type | Article | - |
dc.publisher.location | 미국 | - |
dc.identifier.doi | 10.1021/ma1007144 | - |
dc.identifier.scopusid | 2-s2.0-77955801579 | - |
dc.identifier.wosid | 000279573600006 | - |
dc.identifier.bibliographicCitation | MACROMOLECULES, v.43, no.13, pp 5508 - 5511 | - |
dc.citation.title | MACROMOLECULES | - |
dc.citation.volume | 43 | - |
dc.citation.number | 13 | - |
dc.citation.startPage | 5508 | - |
dc.citation.endPage | 5511 | - |
dc.description.isOpenAccess | N | - |
dc.description.journalRegisteredClass | sci | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.identifier.url | https://pubs.acs.org/doi/10.1021/ma1007144 | - |
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