Reactions of tetrasulfur tetranitride antimony pentachloride complex (S4N4 SbCl5) with primary beta-enaminones and beta-enamino esters: Synthesis of 4-substituted 3-aroyl- and 3-ethoxycarbonyl-1,2,5-thiadiazoles
DC Field | Value | Language |
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dc.contributor.author | Bae, SH | - |
dc.contributor.author | Kim, K | - |
dc.contributor.author | Park, YJ | - |
dc.date.available | 2021-02-22T16:47:34Z | - |
dc.date.issued | 2000-01 | - |
dc.identifier.issn | 0385-5414 | - |
dc.identifier.issn | 1881-0942 | - |
dc.identifier.uri | https://scholarworks.sookmyung.ac.kr/handle/2020.sw.sookmyung/16792 | - |
dc.description.abstract | The reaction of tetrasulfur tetranitride antimony pentachloride complex (S4N4SbCl5) with 3-amino-3-alkyl-1-aryl-2-propenones and 3-amino-1,3-diaryl-2-propenones in toluene at 100 degrees C produced 4-substitued 3-aroyl-1,2,5-thiadiazoles (3a-p) in 12 to 57% yields. Similarly treatment of beta-enamino esters with S4N4SbCl5 complex under the same conditions as for the reaction with beta-enaminones gave ethyl 3-aryl-1,2,5-thiadizole-4-carboxylates (3q-x) in 41 to 54% yields. The formation of the products may be explained by the same mechanism as that proposed for the formation of 1,2,5-thiadizoles from 5-substitued 3-alkyl- and 3-aryl-isoxazoles and S4N4SbCl5 complex. | - |
dc.format.extent | 14 | - |
dc.language | 영어 | - |
dc.language.iso | ENG | - |
dc.publisher | PERGAMON-ELSEVIER SCIENCE LTD | - |
dc.title | Reactions of tetrasulfur tetranitride antimony pentachloride complex (S4N4 SbCl5) with primary beta-enaminones and beta-enamino esters: Synthesis of 4-substituted 3-aroyl- and 3-ethoxycarbonyl-1,2,5-thiadiazoles | - |
dc.type | Article | - |
dc.publisher.location | 영국 | - |
dc.identifier.doi | 10.3987/com-99-8750 | - |
dc.identifier.scopusid | 2-s2.0-0033960212 | - |
dc.identifier.wosid | 000085252000018 | - |
dc.identifier.bibliographicCitation | HETEROCYCLES, v.53, no.1, pp 159 - 172 | - |
dc.citation.title | HETEROCYCLES | - |
dc.citation.volume | 53 | - |
dc.citation.number | 1 | - |
dc.citation.startPage | 159 | - |
dc.citation.endPage | 172 | - |
dc.type.docType | Article | - |
dc.description.isOpenAccess | N | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Organic | - |
dc.subject.keywordPlus | S4N4.SBCL5 | - |
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