Exploiting Dynamic Opening of Apertures in a Partially Fluorinated MOF for Enhancing H-2 Desorption Temperature and Isotope Separation
DC Field | Value | Language |
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dc.contributor.author | Zhang, Linda | - |
dc.contributor.author | Jee, Seohyeon | - |
dc.contributor.author | Park, Jaewoo | - |
dc.contributor.author | Jung, Minji | - |
dc.contributor.author | Wallacher, Dirk | - |
dc.contributor.author | Franz, Alexandra | - |
dc.contributor.author | Lee, Wonjoo | - |
dc.contributor.author | Yoon, Minyoung | - |
dc.contributor.author | Choi, Kyungmin | - |
dc.contributor.author | Hirscher, Michael | - |
dc.contributor.author | Oh, Hyunchul | - |
dc.date.available | 2021-02-22T05:36:19Z | - |
dc.date.issued | 2019-11 | - |
dc.identifier.issn | 0002-7863 | - |
dc.identifier.issn | 1520-5126 | - |
dc.identifier.uri | https://scholarworks.sookmyung.ac.kr/handle/2020.sw.sookmyung/2694 | - |
dc.description.abstract | Deuterium has been recognized as an irreplaceable element in industrial and scientific research. However, hydrogen isotope separation still remains a huge challenge due to the identical physicochemical properties of the isotopes. In this paper, a partially fluorinated metal-organic framework (MOF) with copper, a so-called FMOFCu, was investigated to determine the separation efficiency and capacity of the framework for deuterium extraction from a hydrogen isotope mixture. The unique structure of this porous material consists of a trimodal pore system with large tubular cavities connected through a smaller cavity with bottleneck apertures with a size of 3.6 angstrom plus a third hidden cavity connected by an even smaller aperture of 2.5 angstrom. Depending on the temperature, these two apertures show a gate-opening effect and the cavities get successively accessible for hydrogen with increasing temperature. Thermal desorption spectroscopy (TDS) measurements indicate that the locally flexible MOF can separate D-2 from anisotope mixture efficiently, with a selectivity of 14 at 25 K and 4 at 77 K. | - |
dc.format.extent | 9 | - |
dc.language | 영어 | - |
dc.language.iso | ENG | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | Exploiting Dynamic Opening of Apertures in a Partially Fluorinated MOF for Enhancing H-2 Desorption Temperature and Isotope Separation | - |
dc.type | Article | - |
dc.publisher.location | 미국 | - |
dc.identifier.doi | 10.1021/jacs.9b10268 | - |
dc.identifier.scopusid | 2-s2.0-85076597300 | - |
dc.identifier.wosid | 000503917800044 | - |
dc.identifier.bibliographicCitation | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, v.141, no.50, pp 19850 - 19858 | - |
dc.citation.title | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | - |
dc.citation.volume | 141 | - |
dc.citation.number | 50 | - |
dc.citation.startPage | 19850 | - |
dc.citation.endPage | 19858 | - |
dc.type.docType | Article | - |
dc.description.isOpenAccess | Y | - |
dc.description.journalRegisteredClass | sci | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.subject.keywordPlus | METAL-ORGANIC FRAMEWORKS | - |
dc.subject.keywordPlus | GAS-ADSORPTION | - |
dc.subject.keywordPlus | HYDROGEN | - |
dc.subject.keywordPlus | SITES | - |
dc.subject.keywordPlus | D-2 | - |
dc.identifier.url | https://pubs.acs.org/doi/10.1021/jacs.9b10268 | - |
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