A Manganese(V)-Oxo Tetraamido Macrocyclic Ligand (TAML) Cation Radical Complex: Synthesis, Characterization, and Reactivity Studies
DC Field | Value | Language |
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dc.contributor.author | Karmalkar, Deepika G. | - |
dc.contributor.author | Li, Xiao-Xi | - |
dc.contributor.author | Seo, Mi Sook | - |
dc.contributor.author | Sankaralingam, Muniyandi | - |
dc.contributor.author | Ohta, Takehiro | - |
dc.contributor.author | Sarangi, Ritimukta | - |
dc.contributor.author | Hong, Seungwoo | - |
dc.contributor.author | Nam, Wonwoo | - |
dc.date.available | 2021-02-22T07:46:21Z | - |
dc.date.issued | 2018-12 | - |
dc.identifier.issn | 0947-6539 | - |
dc.identifier.issn | 1521-3765 | - |
dc.identifier.uri | https://scholarworks.sookmyung.ac.kr/handle/2020.sw.sookmyung/4150 | - |
dc.description.abstract | A mononuclear manganese(V)-oxo complex with tetraamido macrocyclic ligand (TAML), [Mn-V(O)(TAML)](-) (1), is a sluggish oxidant in oxidation reactions. Herein, a mononuclear manganese(V)-oxo TAML cation radical complex, [Mn-V(O)(TAML(+.))] (2), is reported. It was synthesized by reacting [Mn-III(TAML)](-) with 3.0 equivalents of [Ru-III(bpy)(3)](3+) or upon addition of one-electron oxidant to 1 and then characterized thoroughly with various spectroscopic techniques along with DFT calculations. Although 1 is a sluggish oxidant, 2 is a strong oxidant capable of activating C-H bonds of hydrocarbons (i.e., hydrogen atom transfer reaction) and transferring its oxygen atom to thioanisoles and olefins (i.e., oxygen atom transfer reaction). | - |
dc.format.extent | 5 | - |
dc.language | 영어 | - |
dc.language.iso | ENG | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.title | A Manganese(V)-Oxo Tetraamido Macrocyclic Ligand (TAML) Cation Radical Complex: Synthesis, Characterization, and Reactivity Studies | - |
dc.type | Article | - |
dc.publisher.location | 독일 | - |
dc.identifier.doi | 10.1002/chem.201804898 | - |
dc.identifier.scopusid | 2-s2.0-85056708710 | - |
dc.identifier.wosid | 000453050900010 | - |
dc.identifier.bibliographicCitation | CHEMISTRY-A EUROPEAN JOURNAL, v.24, no.68, pp 17927 - 17931 | - |
dc.citation.title | CHEMISTRY-A EUROPEAN JOURNAL | - |
dc.citation.volume | 24 | - |
dc.citation.number | 68 | - |
dc.citation.startPage | 17927 | - |
dc.citation.endPage | 17931 | - |
dc.type.docType | Article | - |
dc.description.isOpenAccess | N | - |
dc.description.journalRegisteredClass | sci | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.subject.keywordPlus | COUPLED ELECTRON-TRANSFER | - |
dc.subject.keywordPlus | ATOM TRANSFER REACTIVITY | - |
dc.subject.keywordPlus | OXYGEN-EVOLVING COMPLEX | - |
dc.subject.keywordPlus | H BOND ACTIVATION | - |
dc.subject.keywordPlus | THIOLATE LIGATION | - |
dc.subject.keywordPlus | WATER OXIDATION | - |
dc.subject.keywordPlus | PHOTOSYSTEM-II | - |
dc.subject.keywordPlus | CORROLE | - |
dc.subject.keywordPlus | PROTON | - |
dc.subject.keywordPlus | EPOXIDATION | - |
dc.subject.keywordAuthor | C-H bond activation | - |
dc.subject.keywordAuthor | manganese | - |
dc.subject.keywordAuthor | olefin epoxidation | - |
dc.subject.keywordAuthor | radicals | - |
dc.subject.keywordAuthor | sulfoxidation | - |
dc.identifier.url | https://chemistry-europe.onlinelibrary.wiley.com/doi/full/10.1002/chem.201804898 | - |
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