A Mononuclear Nonheme Iron(V)-Imido Complex
DC Field | Value | Language |
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dc.contributor.author | Hong, Seungwoo | - |
dc.contributor.author | Sutherlin, Kyle D. | - |
dc.contributor.author | Vardhaman, Anil Kumar | - |
dc.contributor.author | Yan, James J. | - |
dc.contributor.author | Park, Sora | - |
dc.contributor.author | Lee, Yong-Min | - |
dc.contributor.author | Jang, Soojeong | - |
dc.contributor.author | Lu, Xiaoyan | - |
dc.contributor.author | Ohta, Takehiro | - |
dc.contributor.author | Ogura, Takashi | - |
dc.contributor.author | Solomon, Edward I. | - |
dc.contributor.author | Nam, Wonwoo | - |
dc.date.available | 2021-02-22T11:12:52Z | - |
dc.date.issued | 2017-07 | - |
dc.identifier.issn | 0002-7863 | - |
dc.identifier.issn | 1520-5126 | - |
dc.identifier.uri | https://scholarworks.sookmyung.ac.kr/handle/2020.sw.sookmyung/8249 | - |
dc.description.abstract | Mononuclear nonheme iron(V)-oxo complexes have been reported previously. Herein, we report the first example of a mononuclear nonheme iron(V)-imido complex bearing a tetraamido macrocyclic ligand (TAML), [(TAML)Fe-V(NTs)](-) (1). The spectroscopic characterization of 1 revealed an S = 1/2 Fe(V) oxidation state, an Fe-N bond length of 1.65(4) angstrom, and an Fe-N vibration at 817 cm(-1). The reactivity of 1 was demonstrated in C-H bond functionalization and nitrene transfer reactions. | - |
dc.format.extent | 4 | - |
dc.language | 영어 | - |
dc.language.iso | ENG | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | A Mononuclear Nonheme Iron(V)-Imido Complex | - |
dc.type | Article | - |
dc.publisher.location | 미국 | - |
dc.identifier.doi | 10.1021/jacs.7b04695 | - |
dc.identifier.scopusid | 2-s2.0-85022056323 | - |
dc.identifier.wosid | 000405158900006 | - |
dc.identifier.bibliographicCitation | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, v.139, no.26, pp 8800 - 8803 | - |
dc.citation.title | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | - |
dc.citation.volume | 139 | - |
dc.citation.number | 26 | - |
dc.citation.startPage | 8800 | - |
dc.citation.endPage | 8803 | - |
dc.type.docType | Article | - |
dc.description.isOpenAccess | N | - |
dc.description.journalRegisteredClass | sci | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.subject.keywordPlus | METAL-OXO COMPLEXES | - |
dc.subject.keywordPlus | OXIDATION REACTIONS | - |
dc.subject.keywordPlus | TRANSFER REACTIVITY | - |
dc.subject.keywordPlus | IRON | - |
dc.subject.keywordPlus | IRON(IV)-OXO | - |
dc.subject.keywordPlus | NITRIDO | - |
dc.subject.keywordPlus | FE | - |
dc.subject.keywordPlus | HYDROXYLATION | - |
dc.subject.keywordPlus | ENVIRONMENTS | - |
dc.subject.keywordPlus | AMINATION | - |
dc.identifier.url | https://pubs.acs.org/doi/10.1021/jacs.7b04695 | - |
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