Single-atom Pd catalyst anchored on Zr-based metal-organic polyhedra for Suzuki-Miyaura cross coupling reactions in aqueous media
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Kim, Seongsoo | - |
dc.contributor.author | Jee, Seohyeon | - |
dc.contributor.author | Choi, Kyung Min | - |
dc.contributor.author | Shin, Dong-Sik | - |
dc.date.available | 2021-02-22T04:56:24Z | - |
dc.date.issued | 2021-02 | - |
dc.identifier.issn | 1998-0124 | - |
dc.identifier.issn | 1998-0000 | - |
dc.identifier.uri | https://scholarworks.sookmyung.ac.kr/handle/2020.sw.sookmyung/849 | - |
dc.description.abstract | The challenge for single-atom catalysts in various C-C cross coupling reaction exists in the development of solid supporting materials. It has been desired to find a supporting material designed in molecular level to anchor a single-atom catalyst and provide high degree of dispersion and substrate access in aqueous media. Here, we prepared discrete cages of metal-organic polyhedra anchoring single Pd atom (MOP-BPY(Pd)) and successfully performed a Suzuki-Miyaura cross coupling reaction with various substrates in aqueous media. It was revealed that each tetrahedral cage of MOP-BPY(Pd) has 4.5 Pd atoms on average and retained its high degree of dispersion up to 3 months in water. The coupling efficiencies of the Suzuki-Miyaura cross coupling reaction exhibited more than 90.0% for various substrates we have tested in the aqueous media, which is superior to those of the molecular Pd complex and metal-organic framework (MOF) anchoring Pd atoms. Moreover, MOP-BPY(Pd) was successfully recovered and recycled without performance degradation. | - |
dc.format.extent | 7 | - |
dc.language | 영어 | - |
dc.language.iso | ENG | - |
dc.publisher | TSINGHUA UNIV PRESS | - |
dc.title | Single-atom Pd catalyst anchored on Zr-based metal-organic polyhedra for Suzuki-Miyaura cross coupling reactions in aqueous media | - |
dc.type | Article | - |
dc.publisher.location | 중국 | - |
dc.identifier.doi | 10.1007/s12274-020-2885-7 | - |
dc.identifier.scopusid | 2-s2.0-85087061019 | - |
dc.identifier.wosid | 000543638700005 | - |
dc.identifier.bibliographicCitation | NANO RESEARCH, v.14, no.2, pp 486 - 492 | - |
dc.citation.title | NANO RESEARCH | - |
dc.citation.volume | 14 | - |
dc.citation.number | 2 | - |
dc.citation.startPage | 486 | - |
dc.citation.endPage | 492 | - |
dc.type.docType | Article; Early Access | - |
dc.description.isOpenAccess | N | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalResearchArea | Science & Technology - Other Topics | - |
dc.relation.journalResearchArea | Materials Science | - |
dc.relation.journalResearchArea | Physics | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Physical | - |
dc.relation.journalWebOfScienceCategory | Nanoscience & Nanotechnology | - |
dc.relation.journalWebOfScienceCategory | Materials Science, Multidisciplinary | - |
dc.relation.journalWebOfScienceCategory | Physics, Applied | - |
dc.subject.keywordPlus | HIGHLY-ACTIVE CATALYSTS | - |
dc.subject.keywordPlus | PALLADIUM NANOPARTICLES | - |
dc.subject.keywordPlus | ARYLBORONIC ACIDS | - |
dc.subject.keywordPlus | HECK REACTION | - |
dc.subject.keywordPlus | GRAPHENE | - |
dc.subject.keywordPlus | OXIDE | - |
dc.subject.keywordPlus | ARYL | - |
dc.subject.keywordPlus | FRAMEWORK | - |
dc.subject.keywordPlus | EFFICIENT | - |
dc.subject.keywordPlus | CHEMISTRY | - |
dc.subject.keywordAuthor | metal-organic polyhedra | - |
dc.subject.keywordAuthor | Suzuki-Miyaura cross coupling reaction | - |
dc.subject.keywordAuthor | structure characterization | - |
dc.subject.keywordAuthor | aqueous phase reaction | - |
dc.subject.keywordAuthor | high-degree of dispersion | - |
dc.identifier.url | https://link.springer.com/article/10.1007%2Fs12274-020-2885-7 | - |
Items in ScholarWorks are protected by copyright, with all rights reserved, unless otherwise indicated.
Sookmyung Women's University. Cheongpa-ro 47-gil 100 (Cheongpa-dong 2ga), Yongsan-gu, Seoul, 04310, Korea02-710-9127
Copyright©Sookmyung Women's University. All Rights Reserved.
Certain data included herein are derived from the © Web of Science of Clarivate Analytics. All rights reserved.
You may not copy or re-distribute this material in whole or in part without the prior written consent of Clarivate Analytics.