Mechanistic Insight into the Nitric Oxide Dioxygenation Reaction of Nonheme Iron(III)-Superoxo and Manganese(IV)-Peroxo Complexes
DC Field | Value | Language |
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dc.contributor.author | 홍승우 | - |
dc.contributor.author | Pankaj KUMAR | - |
dc.contributor.author | 조경빈 | - |
dc.contributor.author | 이용민 | - |
dc.contributor.author | KennethD. KARLIN | - |
dc.contributor.author | 남원우 | - |
dc.date.available | 2021-02-22T11:24:24Z | - |
dc.date.issued | 2016-09 | - |
dc.identifier.issn | 1433-7851 | - |
dc.identifier.issn | 1521-3773 | - |
dc.identifier.uri | https://scholarworks.sookmyung.ac.kr/handle/2020.sw.sookmyung/9415 | - |
dc.description.abstract | Reactions of nonheme FeIII–superoxo and MnIV–peroxo complexes bearing a common tetraamido macrocyclic ligand (TAML), namely [(TAML)FeIII(O2)]2−and [(TAML)MnIV(O2)]2−, with nitric oxide (NO) afford the FeIII–NO3complex [(TAML)FeIII(NO3)]2−and the MnV–oxo complex [(TAML)MnV(O)]−plus NO2−, respectively. Mechanistic studies, including density functional theory (DFT) calculations, reveal that MIII–peroxynitrite (M=Fe and Mn) species, generated in the reactions of [(TAML)FeIII(O2)]2−and [(TAML)MnIV(O2)]2−with NO, are converted into MIV(O) and.NO2species through O−O bond homolysis of the peroxynitrite ligand. Then, a rebound of FeIV(O) with.NO2affords [(TAML)FeIII(NO3)]2−, whereas electron transfer from MnIV(O) to.NO2yields [(TAML)MnV(O)]−plus NO2−. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim | - |
dc.format.extent | 5 | - |
dc.language | 영어 | - |
dc.language.iso | ENG | - |
dc.publisher | John Wiley & Sons Ltd. | - |
dc.title | Mechanistic Insight into the Nitric Oxide Dioxygenation Reaction of Nonheme Iron(III)-Superoxo and Manganese(IV)-Peroxo Complexes | - |
dc.type | Article | - |
dc.publisher.location | 독일 | - |
dc.identifier.doi | 10.1002/anie.201605705 | - |
dc.identifier.scopusid | 2-s2.0-84984908111 | - |
dc.identifier.wosid | 000384713700047 | - |
dc.identifier.bibliographicCitation | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v.55, no.40, pp 12403 - 12407 | - |
dc.citation.title | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | - |
dc.citation.volume | 55 | - |
dc.citation.number | 40 | - |
dc.citation.startPage | 12403 | - |
dc.citation.endPage | 12407 | - |
dc.description.isOpenAccess | N | - |
dc.description.journalRegisteredClass | sci | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.identifier.url | https://onlinelibrary.wiley.com/doi/abs/10.1002%2Fanie.201605705? | - |
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