Efficient, stable silicon tandem cells enabled by anion-engineered wide-bandgap perovskites
  • Kim, Daehan
  • Jung, Hee Joon
  • Park, Ik Jae
  • Larson, Bryon W.
  • Dunfield, Sean P.
  • 외 15명
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초록

Maximizing the power conversion efficiency (PCE) of perovskite/silicon tandem solar cells that can exceed the Shockley-Queisser single-cell limit requires a high-performing, stable perovskite top cell with a wide bandgap. We developed a stable perovskite solar cell with a bandgap of similar to 1.7 electron volts that retained more than 80% of its initial PCE of 20.7% after 1000 hours of continuous illumination. Anion engineering of phenethylammonium-based two-dimensional (2D) additives was critical for controlling the structural and electrical properties of the 2D passivation layers based on a lead iodide framework. The high PCE of 26.7% of a monolithic two-terminal wide-bandgap perovskite/silicon tandem solar cell was made possible by the ideal combination of spectral responses of the top and bottom cells.

키워드

SOLAR-CELLSGAP PEROVSKITES
제목
Efficient, stable silicon tandem cells enabled by anion-engineered wide-bandgap perovskites
저자
Kim, DaehanJung, Hee JoonPark, Ik JaeLarson, Bryon W.Dunfield, Sean P.Xiao, ChuanxiaoKim, JekyungTong, JinhuiBoonmongkolras, PassarutJi, Su GeunZhang, FeiPae, Seong RyulKim, MinkyuKang, Seok BeomDravid, VinayakBerry, Joseph J.Kim, Jin YoungZhu, KaiKim, Dong HoeShin, Byungha
DOI
10.1126/science.aba3433
발행일
2020-04
유형
Article
저널명
Science
368
6487
페이지
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