Boosting the solar water oxidation performance of a BiVO4 photoanode by crystallographic orientation control
- Authors
- Han, Hyun Soo; Shin, Sun; Kim, Dong Hoe; Park, Ik Jae; Kim, Ju Seong; Huang, Po-Shun; Lee, Jung-Kun; Cho, In Sun; Zheng, Xiaolin
- Issue Date
- May-2018
- Publisher
- ROYAL SOC CHEMISTRY
- Citation
- ENERGY ENVIRONMENTAL SCIENCE, v.11, no.5, pp 1299 - 1306
- Pages
- 8
- Journal Title
- ENERGY ENVIRONMENTAL SCIENCE
- Volume
- 11
- Number
- 5
- Start Page
- 1299
- End Page
- 1306
- URI
- https://scholarworks.sookmyung.ac.kr/handle/2020.sw.sookmyung/146213
- DOI
- 10.1039/c8ee00125a
- ISSN
- 1754-5692
1754-5706
- Abstract
- Materials with low crystal symmetry often exhibit anisotropic properties, allowing the tuning of their physical and chemical properties via crystallographic orientation and exposed facet control. Herein, for the first time, we have demonstrated that pristine BiVO4 with a preferred [001] growth orientation and exposed (001) facets exhibits excellent intrinsic charge transport properties and surface reactivity. Using preferentially [001]-oriented BiVO4 (p-BVO) as a photoanode for photoelectrochemical water splitting, an impressive photocurrent density at 1.23 V vs. the reversible hydrogen electrode (RHE) is achieved, which is approximately 16 times higher than that exhibited by a photoanode based on randomly oriented BiVO4. Importantly, when the surface of p-BVO is further roughened and decorated with an oxygen evolution electrocatalyst, photocurrent densities of approximate to 3.5 and approximate to 6.1 mA cm(-2) are achieved at 0.6 and 1.23 V-RHE, respectively; the latter value corresponds to approximate to 82% of the theoretically achievable photocurrent density for BiVO4 under 1 sun illumination. Our results demonstrate the effectiveness of crystal orientation and exposed facet control in optimizing materials for solar water-splitting applications.
- Files in This Item
-
Go to Link
- Appears in
Collections - ICT융합공학부 > 응용물리전공 > 1. Journal Articles
Items in ScholarWorks are protected by copyright, with all rights reserved, unless otherwise indicated.