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‘Cleft-form’ electrochemical anion chemosensor with amide and triazole donor groups
- Issue Date
- Sep-2012
- Publisher
- Elsevier BV
- Keywords
- 'Cleft-form' receptor; Anions sensing; Ferrocene
- Citation
- Tetrahedron Letters, v.53, no.37, pp 4917 - 4920
- Pages
- 4
- Journal Title
- Tetrahedron Letters
- Volume
- 53
- Number
- 37
- Start Page
- 4917
- End Page
- 4920
- ISSN
- 0040-4039
- Abstract
- A novel “cleft-form” electrochemical anions receptor bearing amide and triazole donor groups, 1, has been synthesized and characterized. Among various anions, 1 shows a significant anodic shift response for H2PO4– and F–, with its multiple N-H•••anion and C-H•••anion interactions, which is supported by theoretical calculation and NMR titration results
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