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Palladium Induced Macrocyclic Preorganization for Stabilization of a Tetrathiafulvalene Mixed-Valence Dimer
- Issue Date
- Sep-2011
- Publisher
- AMER CHEMICAL SOC
- Citation
- ORGANIC LETTERS, v.13, no.18, pp 4902 - 4905
- Pages
- 4
- Journal Title
- ORGANIC LETTERS
- Volume
- 13
- Number
- 18
- Start Page
- 4902
- End Page
- 4905
- ISSN
- 1523-7060
1523-7052
- Abstract
- Ditopic metalation of a flexible Pacman-like tetrathiafulvalene (TTF) modified Schiff-base-calixpyrrole results in the stabilization upon oxidation of an otherwise difficult-to-access mixed-valence TTF radical dimer. EPR and optical spectroscopies were used to characterize the mixed-valence species.
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