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Ion-induced FRET on-off in fluorescent calix[4]arene
- Issue Date
- May-2007
- Publisher
- American Chemical Society
- Citation
- Journal of Organic Chemistry, v.72, no.11, pp 4242 - 4245
- Pages
- 4
- Journal Title
- Journal of Organic Chemistry
- Volume
- 72
- Number
- 11
- Start Page
- 4242
- End Page
- 4245
- ISSN
- 0022-3263
1520-6904
- Abstract
- (Chemical Equation Presented) A novel calix[4]arene bearing one 2,3-naphthocrown-6 and two coumarin amide units at the lower rim in partial-cone conformation (1) was synthesized as a colorimetric and FRET-based fluorometric sensor for F- and Cs+ ions. Intramolecular FRET from the naphthalene emission to the coumarin absorption affords high fluorescence selectivity toward F- and Cs+ ions. ？ 2007 American Chemical Society.
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