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Synthesis and structure of a second polymorph of strontium germanium Nitride: beta-Sr2GeN2
- Authors
- Park, DG; Gal, ZA; DiSalvo, FJ
- Issue Date
- May-2005
- Publisher
- KOREAN CHEMICAL SOC
- Keywords
- strontium germanium nitride; polymorph; crystal structure
- Citation
- BULLETIN OF THE KOREAN CHEMICAL SOCIETY, v.26, no.5, pp 786 - 790
- Pages
- 5
- Journal Title
- BULLETIN OF THE KOREAN CHEMICAL SOCIETY
- Volume
- 26
- Number
- 5
- Start Page
- 786
- End Page
- 790
- ISSN
- 0253-2964
1229-5949
- Abstract
- A new ternary strontium germanium nitride, beta-Sr2GeN2, was obtained as single crystal from constituent elements in molten Na. It crystallizes in space group Cmca (No. 64) with a = 5.441 (1) angstrom, b = 11.377(2) A, c = 12.229(2) angstrom, and Z = 8. Its crystal structure is closely related to that of polymorphic companion, alpha-Sr2GeN2, both of which contain isolated bent anions of alpha-Sr2GeN2
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