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Small cavitands specifically binding a water molecule
- Issue Date
- Feb-2004
- Publisher
- AMER CHEMICAL SOC
- Citation
- ORGANIC LETTERS, v.6, no.3, pp 369 - 372
- Pages
- 4
- Journal Title
- ORGANIC LETTERS
- Volume
- 6
- Number
- 3
- Start Page
- 369
- End Page
- 372
- ISSN
- 1523-7060
1523-7052
- Abstract
- Three new C-2v cavitands based on resorcin[4]arene bind water specifically at low temperature in CD2Cl2 or CDCl3 due to their complementarity to water as well as the solvophobic interaction. The averaged AHdegrees and ASdegrees values are -2.3 kcal mol(-1) and -128 cal mol(-1) K-1, which gave the averaged -AGdegrees of 1.9 kcal mol(-1) at -50degreesC in water saturated CD2Cl2.
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