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Novel Ring Contractions via [2,3] Wittig Type Rearrangements: Synthesis of 2-Desoxy-2-methylenebicyclomycin
- Issue Date
- Aug-1991
- Publisher
- American Chemical Society
- Citation
- Journal of the American Chemical Society, v.113, no.17, pp 6621 - 6633
- Pages
- 13
- Journal Title
- Journal of the American Chemical Society
- Volume
- 113
- Number
- 17
- Start Page
- 6621
- End Page
- 6633
- ISSN
- 0002-7863
1520-5126
- Abstract
- Bridgehead carbanion generation of bicyclo[5.2.2] and bicycio[7.2.2] allyl ether bridged piperazinediones result in novel ring contractions via unusual [2,3] Wittig type and [3,3] Claisen rearrangements. The application of the [2,3] Wittig rearrangements to the construction of 2-desoxy-2-methylenebicyclomycin (3) is described. © 1991, American Chemical Society. All rights reserved.
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