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1,3-alternate and C-1,2-alternate tetrahomodioxacalix[4]crowns. Crystal structures and metal ion complexation
- Issue Date
- Jun-2003
- Publisher
- SPRINGER
- Keywords
- calixarene; homooxacalixarene; complexation; X-ray crystal structure
- Citation
- JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY, v.46, no.1-2, pp 97 - 103
- Pages
- 7
- Journal Title
- JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY
- Volume
- 46
- Number
- 1-2
- Start Page
- 97
- End Page
- 103
- ISSN
- 1388-3127
1573-1111
- Abstract
- Two novel tetrahomodioxacalix[4] crowns with crown-5 and crown-6 rings were synthesized. From X-ray crystal structures, homooxacalix[ 4] crown-5 ( 3) and homooxacalix[ 4] crown-6 ( 2) were found to be in the 1,3-alternate and the C-1,2- alternate conformations, respectively. Homooxacalix[ 4] crown-5 ( 1) shows a marked selectivity for cesium ion over other metal ions tested.
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Collections - 이과대학 > 화학과 > 1. Journal Articles
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