Changes in macrocyclic aromaticity and formation of a charge-separated state by complexation of expanded porphyrin and C60
- Authors
- Cha, Won-Young; Ahn, Ahreum; Kim, Taeyeon; Oh, Juwon; Ali, Rashid; Park, Jung Su; Kim, Dongho
- Issue Date
- Jul-2019
- Publisher
- Royal Society of Chemistry
- Citation
- Chemical Communications, v.55, no.57, pp 8301 - 8304
- Pages
- 4
- Journal Title
- Chemical Communications
- Volume
- 55
- Number
- 57
- Start Page
- 8301
- End Page
- 8304
- URI
- https://scholarworks.sookmyung.ac.kr/handle/2020.sw.sookmyung/2936
- DOI
- 10.1039/c9cc03928g
- ISSN
- 1359-7345
1364-548X
- Abstract
- Significant changes of macrocyclic aromaticity in expanded porphyrins through C-60 complexation were studied by H-1 NMR spectroscopy and nucleus-independent chemical shift calculations. This work is a detailed research study of how the formation of a complex of dual aromatic expanded porphyrin with fullerene affects the electron densities in the main conjugation pathways and meso-substituents. Furthermore, we found that the formation of the photoinduced charge-separated state and the triplet excited-state populations of the bowl-shaped and rigid expanded porphyrin can be controlled by a simple complexation with C-60.
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