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Factors that determine thione( thiol)- disulfide interconversion in a bis( thiosemicarbazone) copper( II) complexopen access
- Authors
- Jeong, Haewon; Kang, Yeji; Kim, Jin; Kim, Byung-Kwon; Hong, Seungwoo
- Issue Date
- Mar-2019
- Publisher
- ROYAL SOC CHEMISTRY
- Citation
- RSC ADVANCES, v.9, no.16, pp 9049 - 9052
- Pages
- 4
- Journal Title
- RSC ADVANCES
- Volume
- 9
- Number
- 16
- Start Page
- 9049
- End Page
- 9052
- ISSN
- 2046-2069
- Abstract
- Solvent-, acidity-, and redox-responsive thione(thiol)-disulfide interconversion were achieved by a dinuclear copper(ii) complex bearing a bis(thiosemicarbazone) (bTSC) ligand. The role of copper(ii) ion coordination was rationalized by parallel comparison with a bare bTSC ligand and zinc(ii) bTSC complexes under identical reaction conditions.
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