Detailed Information

Cited 0 time in webofscience Cited 1 time in scopus
Metadata Downloads

Peroxide Bond Cleavage of Nonheme Iron-(Hydro/Alkyl) Peroxo Complexes Induced by Endogenous and Exogenous Factorsopen access

Authors
Jeon, HyeriHong, Seungwoo
Issue Date
Feb-2019
Publisher
CHEMICAL SOC JAPAN
Keywords
Peroxide bond cleavage; Homolysis; Heterolysis
Citation
CHEMISTRY LETTERS, v.48, no.2, pp.80 - 85
Journal Title
CHEMISTRY LETTERS
Volume
48
Number
2
Start Page
80
End Page
85
URI
https://scholarworks.sookmyung.ac.kr/handle/2020.sw.sookmyung/3818
DOI
10.1246/cl.180831
ISSN
0366-7022
Abstract
The O-O bond cleavage of peroxide ligands such as hydroperoxide and alkylperoxide within metalloenzymes has been extensively investigated because this process constitutes the key step of dioxygen activation and cellular respiration in all forms of aerobic organisms. Herein, we have provided mechanistic insights into the O-O bond cleavage of iron-(hydro/alkyl)peroxo complexes that was promoted by endogenous and exogenous factors such as spin-state, axial ligand, and electron donors. It has been shown that these factors can effectively direct the O-O bond cleaving pathways (e.g., Fe-O bond cleavage vs O-O bond cleavage or homolysis vs heterolysis). These results support that the peroxide bond cleavage process might proceed via diverse pathways under biological reaction conditions.
Files in This Item
Go to Link
Appears in
Collections
이과대학 > 화학과 > 1. Journal Articles

qrcode

Items in ScholarWorks are protected by copyright, with all rights reserved, unless otherwise indicated.

Related Researcher

Researcher Hong, Seung Woo photo

Hong, Seung Woo
이과대학 (화학과)
Read more

Altmetrics

Total Views & Downloads

BROWSE