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The formation of right-handed and left-handed chiral nanopores within a single domain during amino acid self-assembly on Au(111)

Authors
Yang, SenaJeon, AramDriver, Russell W.Kim, YeonwooJean, Eun HeeKim, SehunLee, Hee-SeungLee, Hangil
Issue Date
Jun-2016
Publisher
ROYAL SOC CHEMISTRY
Citation
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, v.18, no.21, pp 14172 - 14176
Pages
5
Journal Title
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
Volume
18
Number
21
Start Page
14172
End Page
14176
URI
https://scholarworks.sookmyung.ac.kr/handle/2020.sw.sookmyung/9766
DOI
10.1039/c6cp01914e
ISSN
1463-9076
1463-9084
Abstract
We report the formation of both right- and left-handed chiral nanopores within a single domain during the self-assembly of an amino acid derivative on an inert Au(111) surface using STM. DFT calculations employed to rationalize this unusual result identified that intermolecular interactions between chiral, windmill-shaped tetramers are crucial for self-assembly.
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